Abstarct: 1,2,3-triazoles have several biological properties. So, providing a new methodology and synthesis of new derivatives are of interest. In this project, firstly Cu+2-Ethylenediamine complex as a novel heterogeneous catalyst was immobilized on PVC, then its application in synthesis of 1,2,3-triazole was studied. Multiple component reactions of propargyl bromide, amine and aromatic azide in the presence of PVC-EDA-Cu+2 as a catalyst and sodium ascorbate as a reducing agent in water at ambient temperature was produced 4-((1-(aryl)-H-1,2,3-triazole-4-yle)methyl)amine in 82-94% yeilds. Moreover, compound of 4-((1-(aryl)-H-1,2,3-triazole-4-yle)methoxy)benzaldehyde was produced with high yields from the reaction of propargyl ether with aromatic azide in the presence of PVC-EDA-Cu+2 in magnetiged water. The advantages of this method consist of using water as a green solvent, high yields, short reaction time and recycablity of the catalyst.