QD142 : Preparation and characterization of Vanadium and Molybdenum complexes containing chelating thiosemicarbazide and investigation of Its catalytic epoxidation of Alkenes
Thesis > Central Library of Shahrood University > Chemistry > MSc > 2012
Authors:
Abstarct: The subject of this thesis is due to the synthesis of oxovanadium (IV) complexes of dehydroacetic acid thiosemicarbazone [VO(dhatsc)]n and oxomolybdenum (VI) complexes of dehydroacetic acid thiosemicarbazone [MoO2 (dhatsc)]n which characterized by spectroscopic techniques. These catalysts were used for alkens epoxidation. The effect of some reaction parameters such as solvent and oxidant were investigated. It was found that chloroform acted as the best solvent and tert- butyl hydroperoxide as the most favored oxidant.
Keywords:
#dehydroacetic acid thiosemicarbazone #oxovanadium (IV) complex #oxomolybdenum (VI) complex #epoxidation of alkens #tert- butyl hydroperoxide Link
Keeping place: Central Library of Shahrood University
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Keeping place: Central Library of Shahrood University
Visitor:
